Asymmetrization of meso-1,3-diols utilising Pseudomonas fluorescens lipase

被引:20
作者
Alexandre, FR [1 ]
Huet, F [1 ]
机构
[1] Univ Maine, Fac Sci, CNRS, UPRES A 6011,Lab Synth Organ, F-72085 Le Mans 9, France
关键词
D O I
10.1016/S0957-4166(98)00237-7
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A convenient and enantioselective synthesis of monoacetates of meso-1,3-diols 2-substituted with an alkoxymethyl or a thiophenylmethyl group, by enzyme catalyzed acylation, is described. The absolute stereochemistries of two monoacetates were assigned by chemical correlation. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:2301 / 2310
页数:10
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