Heteroleptic Tm(II) complexes: One more success for Trofimenko's scorpionates

被引：65

作者：

Cheng, Jianhua ^{[1
]}

Takats, Josef ^{[1
]}

Ferguson, Michael J. ^{[1
]}

McDonald, Robert ^{[1
]}

机构：

[1] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 05期

关键词：

D O I：

10.1021/ja0776273

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of Tml(2)(THF)(x) with the bulky scorpionate, KTp(tBU,Me), gave (Tp(tBu,Me))Tml(THF) (1). Complex 1 proved to be a useful starting material for a select number of heteroleptic Tm(II) compounds, (Tp(tBu,Me))TmER, including the first Tm(II)-hydrocarbyl derivative, (Tp(tBu,Me))Tm(CH(SiMe3)(2)) (2).

引用

页码：1544 / +

页数：3

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