Mechanism of the Delithiation/Lithiation Process in LiFe0.4Mn0.6PO4: in Situ and ex Situ Investigations on Long-Range and Local Structures

被引：51

作者：

Bezza, Ilharn ^{[1
,2
]}

Kaus, Maximilian ^{[2
]}

Heinzmann, Ralf ^{[3
]}

Yavuz, Murat ^{[2
,4
,7
]}

Knapp, Michael ^{[2
,4
]}

Mangold, Stefan ^{[6
]}

Doyle, Stephen ^{[6
]}

Grey, Clare P. ^{[5
]}

Ehrenberg, Helmut ^{[2
,4
]}

Indris, Sylvio ^{[2
,4
]}

Saadoune, Ismael ^{[1
]}

机构：

[1] Univ Cadi Ayyad, FST Marrakech, LCME, Marrakech 40000, Morocco

[2] Karlsruhe Inst Technol, IAM, D-76344 Karlsruhe, Germany

[3] Bruker Biospin GmbH, D-762870 Rheinstetten, Germany

[4] Helmholtz Inst Ulm Electrochem Energy Storage HIU, D-89069 Ulm, Germany

[5] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

[6] Karlsruhe Inst Technol, ANKA Synchrotron Radiat Facil, D-76021 Karlsruhe, Germany

[7] Tech Univ Darmstadt, Mat Sci, D-64287 Darmstadt, Germany

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2015年 / 119卷 / 17期

关键词：

CATHODE MATERIALS; MAS NMR; ELECTROCHEMICAL PERFORMANCE; PHOSPHO-OLIVINES; LIFEPO4; SPECTROSCOPY; BATTERIES; CARBON; DIFFRACTION;

D O I：

10.1021/jp513032r

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

LiFe0.4Mn0.6PO4 olivine was prepared by a sol-gel route, using citric acid as a chelating agent and NH4H2PO4 as a phosphorus source. Sucrose was used as the Source for the carbon-coating of the particles. The correlation between the physicochemical and the electrochemical properties of this positive electrode material was investigated. The electrochemical tests showed an initial discharge Capacity of 121 mAh/g at a C/20 rate with a good reversibility of the lithiation/delithiation reactions. In situ XRD on LixFe0.4Mn0.6PO4 reveals the occurrence of new phases upon cycling, which disappeared again at the end of discharge. The Single phase observed after one complete cycle is identical to the pristine one. In situ XAS spectroscopy in combination with Fe-57 Mossbauer and Li-7 NMR spectroscopy were used to investigate the changes in the local structure and the oxidation states of the transition metals and thus to complete the overall characterization of the lithiation/delithiation Mechanism. All results reveal a high reversibility of the reactions in this electrode material.

引用

页码：9016 / 9024

页数：9

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