Recent Progress of Hybrid Solid-State Electrolytes for Lithium Batteries

被引：196

作者：

Liu, Xiaoyan ^{[1
,2
]}

Li, Xinru ^{[3
,4
]}

Li, Hexing ^{[1
,2
]}

Wu, Hao Bin ^{[3
]}

机构：

[1] Shanghai Normal Univ, Dept Chem, Educ Minist, Key Lab Resource Chem, Shanghai 200234, Peoples R China

[2] Shanghai Normal Univ, Dept Chem, Shanghai Key Lab Rare Earth Funct Mat, Shanghai 200234, Peoples R China

[3] Zhejiang Univ, Sch Mat Sci & Engn, Hangzhou 310027, Zhejiang, Peoples R China

[4] Univ Calif Los Angeles, Dept Chem & Biomol Engn, Los Angeles, CA USA

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2018年 / 24卷 / 69期

基金：

中国博士后科学基金;

关键词：

hybrid materials; ionic conductivity; lithium metal anode; solid lithium batteries; solid-state electrolyte; METAL-ORGANIC FRAMEWORK; ION-CONDUCTING MEMBRANE; POLYMER ELECTROLYTES; COMPOSITE ELECTROLYTE; IONOGEL ELECTROLYTE; LIQUID; NANOPARTICLES; PERFORMANCE; TRANSPORT; CAPACITY;

D O I：

10.1002/chem.201803616

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Conventional liquid electrolytes for lithium batteries usually suffer from irreversible decomposition and safety concerns. Solid state electrolytes (SSEs) have been considered as the key for advanced lithium batteries with improved energy density and safety, whereas challenges remain for polymer and inorganic SSEs. Recently, hybrid solid-state electrolytes (HSSEs) that integrate the merits of different electrolyte systems have been under intensive study. Herein, we summarize the recent progress of HSSEs with different compositions and structures. The design principle of each type of HSSEs are discussed, as well as their ionic conducting mechanism, electrochemical performance and effects of compositional/structural control. Finally, challenges and perspectives are provided for the future development of HSSEs and solid-state lithium batteries.

引用

页码：18293 / 18306

页数：14

共 107 条

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