Mono-(pentafluorophenyl)porphyrins - Useful intermediates in the regioselective synthesis of multifunctionalised porphyrins

被引:55
作者
Shaw, SJ [1 ]
Elgie, KJ [1 ]
Edwards, C [1 ]
Boyle, RW [1 ]
机构
[1] Univ Essex, Dept Sci Biol, Colchester CO4 3SQ, Essex, England
关键词
D O I
10.1016/S0040-4039(98)02653-7
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A method is presented for coupling meso-phenylporphyrins bearing a single pentafluorophenyl ring to thiol substituted molecules. Mild reaction conditions are conducive to the employment of a wide range of thiols including biologically active moieties. Both diphenyl- and tetraphenylporphyrins bearing a variety of different substituents on the non-fluorinated rings have been used to demonstrate the wide applicability of the method. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1595 / 1596
页数:2
相关论文
共 5 条