Large-scale synthesis and field emission properties of vertically oriented CuO nanowire films

被引:348
作者
Zhu, YW
Yu, T
Cheong, FC
Xui, XJ
Lim, CT
Tan, VBC
Thong, JTL
Sow, CH
机构
[1] Natl Univ Singapore, Dept Phys, Singapore 117542, Singapore
[2] Natl Univ Singapore, Nanosci & Nanotechnol Initiat, Singapore 117542, Singapore
[3] Natl Univ Singapore, Dept Mech Engn, Singapore 117576, Singapore
[4] Natl Univ Singapore, Fac Engn, Ctr Integrated Circuit Failure Anal & Reliabil, Singapore 117576, Singapore
关键词
D O I
10.1088/0957-4484/16/1/018
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Using a simple method of direct heating of bulk copper plates in air, oriented CuO nanowire films were synthesized on a large scale. The length and density of nanowires could be controlled by growth temperature and growth time. Field emission (FE) measurements of CuO nanowire films show that they have a low turn-on field of 3.5-4.5 V mum(-1) and a large current density of 0.45 mA cm(-2) under an applied field of about 7 V mum(-1). By comparing the FE properties of two types of samples with different average lengths and densities (30 mum, 10(8) cm(-2) and 4 mum, 4 x 10(7) cm(-2), respectively), we found that the large length-radius ratio of CuO nanowires effectively improved the local field, which was beneficial to field emission. Verified with finite element calculation, the work function of oriented CuO nanowire films was estimated to be 2.5-2.8 eV.
引用
收藏
页码:88 / 92
页数:5
相关论文
共 22 条
[1]   Carbon nanotubes - the route toward applications [J].
Baughman, RH ;
Zakhidov, AA ;
de Heer, WA .
SCIENCE, 2002, 297 (5582) :787-792
[2]   Field emission from carbon nanotubes:: the first five years [J].
Bonard, JM ;
Kind, H ;
Stöckli, T ;
Nilsson, LA .
SOLID-STATE ELECTRONICS, 2001, 45 (06) :893-914
[3]  
Bonard JM, 2001, ADV MATER, V13, P184, DOI 10.1002/1521-4095(200102)13:3<184::AID-ADMA184>3.0.CO
[4]  
2-I
[5]   Field emission from carbon nanotubes:: perspectives for applications and clues to the emission mechanism [J].
Bonard, JM ;
Salvetat, JP ;
Stöckli, T ;
Forró, L ;
Châtelain, A .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 1999, 69 (03) :245-254
[6]   Temperature dependence of field emission from cupric oxide nanobelt films [J].
Chen, J ;
Deng, SZ ;
Xu, NS ;
Zhang, WX ;
Wen, XG ;
Yang, SH .
APPLIED PHYSICS LETTERS, 2003, 83 (04) :746-748
[7]   Effect of structural parameter on field emission properties of semiconducting copper sulphide nanowire films [J].
Chen, J ;
Deng, SZ ;
She, JC ;
Xu, NS ;
Zhang, WX ;
Wen, XG ;
Yang, SH .
JOURNAL OF APPLIED PHYSICS, 2003, 93 (03) :1774-1777
[8]   Enhanced electron emission from carbon nanotubes through density control using in situ plasma treatment of catalyst metal [J].
Choi, JH ;
Choi, SH ;
Han, JH ;
Yoo, JB ;
Park, CY ;
Jung, T ;
Yu, SG ;
Han, IT ;
Kim, JM .
JOURNAL OF APPLIED PHYSICS, 2003, 94 (01) :487-490
[9]   A CARBON NANOTUBE FIELD-EMISSION ELECTRON SOURCE [J].
DEHEER, WA ;
CHATELAIN, A ;
UGARTE, D .
SCIENCE, 1995, 270 (5239) :1179-1180
[10]   FIELD-EMISSION ENERGY-DISTRIBUTION (FEED) [J].
GADZUK, JW ;
PLUMMER, EW .
REVIEWS OF MODERN PHYSICS, 1973, 45 (03) :487-548