A novel synthetic protocol for poly(fluorenylenevinylene)s: a cascade Suzuki-Heck reaction

被引：34

作者：

Grisorio, R ^{[1
]}

Mastrorilli, P ^{[1
]}

Nobile, CF ^{[1
]}

Romanazzi, G ^{[1
]}

Suranna, GP ^{[1
]}

机构：

[1] Polytech Bari, Dept Water Engn & Chem, I-70125 Bari, Italy

来源：

TETRAHEDRON LETTERS | 2005年 / 46卷 / 15期

关键词：

poly(fluorenylenevinytene)s; potassium vinyltrifluoroborate; Suzuki coupling; Heck coupling;

D O I：

10.1016/j.tetlet.2005.02.090

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This article reports the use of a cascade Suzuki-Heck reaction for the polymerization of suitable aryldibromides with potassium vinyltrifluoroborate resulting in the synthesis of a series of poly(fluorenylenevinylene)s. The protocol is characterized by a great versatility, deriving from the use of easily attainable substrates, and yields polymers with low percentages of structural 1,1-diarylenevinylene defects. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：2555 / 2558

页数：4

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