Desulfurization of biotin and epibiotin sulfoxides with nickel boride:: Analysis of the stereoselectivity through [2H] NMR in a polypeptide liquid crystal

被引：4

作者：

Escalettes, F

Florentin, D

Marquet, A

Canlet, C

Courtieu, J

机构：

[1] Univ Paris 06, CNRS, UMR 7613, Lab Chim Organ Biol, F-75252 Paris 05, France

[2] Univ Paris Sud, ICMO, CNRS URA 1384, Chim Organ Struct Lab, F-91405 Orsay, France

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 41期

关键词：

D O I：

10.1016/S0040-4039(98)01625-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reduction of biotin or epibiotin sulfoxides with nicker boride and deuterated reagents affords as major products bideuterated dethiobiotin. Deuterium localisation by [H-2] NMR in a chiral liquid crystal allows the analysis of the stereoselectivity of the reaction (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：7499 / 7502

页数：4

共 8 条

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