Swelling and elasticity of hydrogels based on poly(ethylene oxide) macroinimer

被引:19
作者
Melekaslan, D
Kasapoglu, F
Ito, K
Yagci, Y
Okay, O [1 ]
机构
[1] Tech Univ Istanbul, Dept Chem, TR-80626 Istanbul, Turkey
[2] Toyohashi Univ Technol, Dept Mat Sci, Toyohashi, Aichi 4418580, Japan
关键词
poly(ethylene oxide); macroinimer; hydrogel; swelling; elasticity;
D O I
10.1002/pi.1334
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
7A novel method for the preparation of hydrogels based on poly(ethylene oxide) (PEO) is presented. A PEO macroinimer possessing both polymerizable and radical generation sites was used to obtain hydrogels having dangling PEO chains. It was shown that PEO macroinimer acts during photopolymerization, both as a monomer and a crosslinker and thus, leads to the formation of hydrogels of various swelling capacities and moduli of elasticity. (C) 2004 Society of Chemical Industry.
引用
收藏
页码:237 / 242
页数:6
相关论文
共 14 条
[1]   EFFECT OF INITIAL TOTAL MONOMER CONCENTRATION ON THE SWELLING BEHAVIOR OF CATIONIC ACRYLAMIDE-BASED HYDROGELS [J].
BAKER, JP ;
HONG, LH ;
BLANCH, HW ;
PRAUSNITZ, JM .
MACROMOLECULES, 1994, 27 (06) :1446-1454
[2]  
Belcheva N, 1997, J POLYM SCI POL CHEM, V35, P1819
[3]   Acrylamide/2-acrylamido-2-methylpropane sulfonic acid sodium salt-based hydrogels: synthesis and characterization [J].
Durmaz, S ;
Okay, O .
POLYMER, 2000, 41 (10) :3693-3704
[4]  
Flory P J., PRINCIPLES POLYM CHE
[5]  
Funke W, 1998, ADV POLYM SCI, V136, P139
[6]  
Lin WP, 1998, J POLYM SCI POL CHEM, V36, P979, DOI 10.1002/(SICI)1099-0518(19980430)36:6<979::AID-POLA13>3.0.CO
[7]  
2-I
[8]   Release behavior of high molecular weight solutes from poly(ethylene glycol)-based degradable networks [J].
Lu, SX ;
Anseth, KS .
MACROMOLECULES, 2000, 33 (07) :2509-2515
[9]   Charge density dependence of elastic modulus of strong polyelectrolyte hydrogels [J].
Okay, O ;
Durmaz, S .
POLYMER, 2002, 43 (04) :1215-1221
[10]   Structural characteristics and swelling behavior of poly(ethylene glycol) diacrylate hydrogels [J].
Padmavathi, NC ;
Chatterji, PR .
MACROMOLECULES, 1996, 29 (06) :1976-1979