Unexpected high levels of NO observed at South Pole

被引:155
作者
Davis, D [1 ]
Nowak, JB
Chen, G
Buhr, M
Arimoto, R
Hogan, A
Eisele, F
Mauldin, L
Tanner, D
Shetter, R
Lefer, B
McMurry, P
机构
[1] Georgia Inst Technol, Sch Earth & Atmospher Sci, Atlanta, GA 30332 USA
[2] New Mexico State Univ, Carlsbad, NM USA
[3] Geochem Sci Div, Hanover, NH USA
[4] Natl Ctr Atmospher Res, Boulder, CO 80307 USA
[5] Univ Minnesota, Minneapolis, MN USA
关键词
D O I
10.1029/2000GL012584
中图分类号
P [天文学、地球科学];
学科分类号
07 ;
摘要
Reported here are the first Austral summer measurements of NO at South Pole (SP). They are unique in that the levels are one to two orders of magnitude higher (i.e., median, 225 pptv) than measured at other polar sites. The available evidence suggests that these elevated levels are the result of photo denitrification of the snowpack, in conjunction with a very thin atmospheric mixing depth, Important chemical consequences included finding the atmospheric oxidizing power at SP to be an order of magnitude higher than expected.
引用
收藏
页码:3625 / 3628
页数:4
相关论文
共 22 条
  • [1] BIOGENIC SULFUR EMISSIONS FROM THE SUB-ANTARCTIC AND ANTARCTIC OCEANS
    BERRESHEIM, H
    [J]. JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1987, 92 (D11): : 13245 - 13262
  • [2] Sulfur Chemistry in the Antarctic Troposphere Experiment: An overview of project SCATE
    Berresheim, H
    Eisele, FL
    [J]. JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1998, 103 (D1) : 1619 - 1627
  • [3] Assessment of upper tropospheric HOx sources over the tropical Pacific based on NASA GTE/PEM data:: Net effect on HOx and other photochemical parameters
    Crawford, J
    Davis, D
    Olson, J
    Chen, G
    Liu, S
    Gregory, G
    Barrick, J
    Sachse, G
    Sandholm, S
    Heikes, B
    Singh, H
    Blake, D
    [J]. JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1999, 104 (D13) : 16255 - 16273
  • [4] DMS oxidation in the Antarctic marine boundary layer:: Comparison of model simulations and field observations of DMS, DMSO, DMSO2, H2SO4(g), MSA(g), and MSA(p)
    Davis, D
    Chen, G
    Kasibhatla, P
    Jefferson, A
    Tanner, D
    Eisele, F
    Lenschow, D
    Neff, W
    Berresheim, H
    [J]. JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1998, 103 (D1) : 1657 - 1678
  • [5] Recent climate anomalies and their impact on snow chemistry at South Pole, 1987-1994
    Dibb, JE
    Whitlow, SI
    [J]. GEOPHYSICAL RESEARCH LETTERS, 1996, 23 (10) : 1115 - 1118
  • [6] PAST VOLCANISM REVEALED BY GREENLAND ICE SHEET IMPURITIES
    HAMMER, CU
    [J]. NATURE, 1977, 270 (5637) : 482 - 486
  • [7] Hogan A.W., 1993, ANTARCT RES SER, V61, P175
  • [8] Release of NOx from sunlight-irradiated midlatitude snow
    Honrath, RE
    Peterson, MC
    Dziobak, MP
    Dibb, JE
    Arsenault, MA
    Green, SA
    [J]. GEOPHYSICAL RESEARCH LETTERS, 2000, 27 (15) : 2237 - 2240
  • [9] Evidence of NOx production within or upon ice particles in the Greenland snowpack
    Honrath, RE
    Peterson, MC
    Guo, S
    Dibb, JE
    Shepson, PB
    Campbell, B
    [J]. GEOPHYSICAL RESEARCH LETTERS, 1999, 26 (06) : 695 - 698
  • [10] OH photochemistry and methane sulfonic acid formation in the coastal Antarctic boundary layer
    Jefferson, A
    Tanner, DJ
    Eisele, FL
    Davis, DD
    Chen, G
    Crawford, J
    Huey, JW
    Torres, AL
    Berresheim, H
    [J]. JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1998, 103 (D1) : 1647 - 1656