Palladium catalysed ter- and tetra-molecular queuing processes. One-pot routes to 3-spiro-2-oxindoles and 3-spiro-2(3H)-benzofuranones.

被引：38

作者：

Grigg, R ^{[1
]}

Putnikovic, B ^{[1
]}

Urch, CJ ^{[1
]}

机构：

[1] ZENECA AGROCHEM,JEALOTTS HILL RES STN,BRACKNELL RG12 6EY,BERKS,ENGLAND

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 05期

关键词：

D O I：

10.1016/0040-4039(95)02245-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The palladium catalysed reactions of 2-halophenols and -anilines with vinyl halides or triflates and CO(1atm) generates 3-spiro-2-oxindoles and 3-spiro-2(3 H)-benzofuranones. Analogous tetramolecular reactions employing norbornenyl triflate and organo-tin(IV) or -boron(III) reagents allow additional functionality to be incorporated regio- and stereo-specifically.

引用

页码：695 / 698

页数：4

共 33 条

[1] PALLADIUM-CATALYZED POLYENE CYCLIZATIONS OF DIENYL ARYL IODIDES
ABELMAN, MM
OVERMAN, LE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (07) : 2328 - 2329
[2] INTRAMOLECULAR ALKENE ARYLATIONS FOR RAPID ASSEMBLY OF POLYCYCLIC SYSTEMS CONTAINING QUATERNARY CENTERS - A NEW SYNTHESIS OF SPIROOXINDOLES AND OTHER FUSED AND BRIDGED RING-SYSTEMS
ABELMAN, MM
OH, T
OVERMAN, LE
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (18) : 4130 - 4133
[3] INTIMATE MECHANISM OF OXIDATIVE ADDITION TO ZEROVALENT PALLADIUM COMPLEXES IN THE PRESENCE OF HALIDE-IONS AND ITS RELEVANCE TO THE MECHANISM OF PALLADIUM-CATALYZED NUCLEOPHILIC SUBSTITUTIONS
AMATORE, C
JUTAND, A
SUAREZ, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (21) : 9531 - 9541
[4] ROLE AND EFFECTS OF HALIDE-IONS ON THE RATES AND MECHANISMS OF OXIDATIVE ADDITION OF IODOBENZENE TO LOW-LIGATED ZEROVALENT PALLADIUM COMPLEXES PD0(PPH3)2
AMATORE, C
AZZABI, M
JUTAND, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (22) : 8375 - 8384
[5] ANACARDIO R, 1995, SYNTHESIS-STUTTGART, P831
[6] CATALYTIC ASYMMETRIC-SYNTHESIS OF QUARTERNARY CARBON CENTERS - PALLADIUM-CATALYZED FORMATION OF EITHER ENANTIOMER OF SPIROOXINDOLES AND RELATED SPIROCYCLICS USING A SINGLE ENANTIOMER OF A CHIRAL DIPHOSPHINE LIGAND
ASHIMORI, A
OVERMAN, LE
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (17) : 4571 - 4572
[7] ABOUT THE SYNTHESIS OF HETEROCYCLIC-ANALOGS OF MARGINALIN AND THEIR TRANSFORMATION PRODUCTS
BARBIER, M
[J]. SYNTHETIC COMMUNICATIONS, 1991, 21 (22) : 2317 - 2327
[8] Bindra J. S., 1973, ALKALOIDS, V14
[9] PALLADIUM-CATALYZED CYCLIZATION CARBOFORMYLATION - MOLECULAR QUEUING CASCADES
BROWN, S
CLARKSON, S
GRIGG, R
SRIDHARAN, V
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (11) : 1135 - 1136
[10] RECENT DEVELOPMENTS AND NEW PERSPECTIVES IN THE HECK REACTION
CABRI, W
CANDIANI, I
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (01) : 2 - 7

← 1 2 3 4 →