Monodispersed NiO nanoflowers with anomalous magnetic behavior

被引:35
作者
Ge, M. Y. [1 ,2 ]
Han, L. Y. [3 ]
Wiedwald, U. [3 ]
Xu, X. B. [1 ,2 ]
Wang, C. [1 ,2 ]
Kuepper, K. [3 ]
Ziemann, P. [3 ]
Jiang, J. Z. [1 ,2 ]
机构
[1] Zhejiang Univ, ICNSM, Hangzhou 310027, Peoples R China
[2] Zhejiang Univ, LNSM, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China
[3] Univ Ulm, Inst Festkorperphys, D-89081 Ulm, Germany
基金
中国国家自然科学基金;
关键词
X-RAY-ABSORPTION; COERCIVITY ENHANCEMENT; CATALYTIC-ACTIVITY; HIGH-DENSITY; NANOPARTICLES; PHOTOEMISSION; DICHROISM; POLARIZATION; SPECTRA; SYSTEMS;
D O I
10.1088/0957-4484/21/42/425702
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Nickel oxide (NiO) nanoflowers, prepared by thermal decomposition, exhibit anomalous magnetic properties far below the blocking temperature, i.e., a cusp in both the zero-field-cooled and field-cooled curves at about 21 K. Detailed characterization discloses that the individual NiO nanoflower consists of porous crystals with holes (1.0-1.5 nm in size) inside. We believe that the low temperature magnetic feature observed here could be a new kind of spin transition for the uncompensated spins around the holes and will trigger more studies in other nanostructured antiferromagnetic materials.
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页数:5
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