Tuning the fluorous partition coefficients of organometallic complexes, The synthesis and characterization of [η5-C5H4CH2CH2(CF2)9CF3]Rh(CO)L (L = CO or P[CH2CH2(CF2)5CF3]3) and Cl2Ni{P[CH2CH2(CF2)5CF3]3}2

被引：63

作者：

Herrera, V

de Rege, PJF

Horvath, IT ^{[1
]}

Le Husebo, T

Hughes, RP

机构：

[1] Dartmouth Coll, Dept Chem, Hanover, NH 03755 USA

[2] Exxon Res & Engn Co, Corp Res, Annandale, NJ 08801 USA

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 1998年 / 1卷 / 06期

关键词：

fluorous partition; fluorous complexes; rhodium complexes; nickel complexes;

D O I：

10.1016/S1387-7003(98)00053-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[eta(5)-C5H4(CH2CH2(CF2)(9)CF3]Rh(CO)L (L = CO (1) or P[CH2CH2(CF2)(5)CF3](3) (2)) and Cl2Ni{P[CH2CH2(CF2)(5)CF3](3)}(2) (3) were prepared and characterized. The fluorous partition coefficients (P-FBS=c(Fluorous) (phase)/c(Other phase)) of 1 (P-FBS=0.8), 2 (P-FBS=29), and 3 (P-FBS = 83) for the c-C6F11CF3/toluene fluorous biphase system (FBS) show that P-FBS can be increased significantly by increasing the number of perfluoroalkyl groups attached to the ligands. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：197 / 199

页数：3

共 8 条

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