The synthesis of L-proline derived tetraazamacrocyclic ligands of C2 symmetry via intramolecular ester aminolysis

被引：18

作者：

Achmatowicz, M

Jurczak, J

机构：

[1] Polish Acad Sci, Inst Organ Chem, PL-01224 Warsaw, Poland

[2] Univ Warsaw, Dept Chem, PL-02093 Warsaw, Poland

来源：

TETRAHEDRON-ASYMMETRY | 2001年 / 12卷 / 01期

关键词：

D O I：

10.1016/S0957-4166(01)00012-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A convenient and efficient synthesis of enantiomerically pure 12-. 14-, and 16-membered tetraazamacrocyclic ligands, able to form complexes with transition metal cations, is discussed. Linear alpha,omega -aminoesters, prepared from L-proline, undergo intramolecular aminolysis to afford the corresponding macrocyclic amides in good yields. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：111 / 119

页数：9

共 31 条

[1]

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[2]

Bhappacharya S., 1986, INORG CHEM, V25, P3448

[3] Nickel-catalyzed oxidations: From hydrocarbons to DNA [J].