A switchable NLO organic-inorganic compound based on conformationally chiral disulfide molecules and Bi(III)I5 iodobismuthate networks

被引：232

作者：

Bi, Wenhua ^{[1
]}

Louvain, Nicolas ^{[1
]}

Mercier, Nicolas ^{[1
]}

Luc, Jerome ^{[2
]}

Rau, Ileana ^{[2
]}

Kajzar, Francois ^{[2
]}

Sahraoui, Bouchta ^{[2
]}

机构：

[1] Univ Angers, CNRS, UMR 6200, Lab Chim Ingn Mol & Mat Angers, F-49045 Angers, France

[2] Univ Angers, CNRS, UMR 6136, Lab Proprietes Opt Mat & Applicat, F-49045 Angers, France

来源：

ADVANCED MATERIALS | 2008年 / 20卷 / 05期

关键词：

D O I：

10.1002/adma.200701753

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel organic-inorganic hybrid based on cystamine and BiI5 chains is prepared. Due to the flexibility of the disulfide molecules in the structure, single crystals or crystalline thin films of this hybrid undergo a reversible acentric-tocentric structural transition at moderate conditions (T=36.8 degrees C). This makes the title compound an excellent candidate for temperature controlled SHG or THG switches.

引用

页码：1013 / +

页数：6

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