Controlling the dimensions, reactivity and crystallinity of multiwalled carbon nanotubes using low ethanol concentrations

被引:61
作者
Botello-Mendez, Andres [1 ]
Campos-Delgado, Jessica [1 ]
Morelos-Gomez, Aaron [1 ]
Romo-Herrera, Jose M. [1 ]
Rodriguez, Angel G. [2 ]
Navarro, Hugo [2 ]
Vidal, Miguel A. [2 ]
Terrones, Humberto [1 ]
Terrones, Mauricio [1 ]
机构
[1] IPICYT, Adv Mat Dept, San Luis Potosi 78216, Mexico
[2] IICO, Optoelect Mat, San Luis Potosi 78210, Mexico
关键词
D O I
10.1016/j.cplett.2007.12.073
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We study the role of ethanol in the thermolytic synthesis of multiwalled carbon nanotubes. We show that low concentrations of ethanol control the length and diameter, as well as the crystalline quality of the produced nanotubes. We statistically evaluated the dimensions of the tubes as the concentration of ethanol is increased. The quality of the samples results in more crystalline products when low concentrations of ethanol (similar to 1-2%) are used in the experiments. In addition, the introduction of ethanol during the synthesis seems to incorporate coordination groups on the surface of nanotubes that cause an enhanced reactivity and a better solubility. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:55 / 61
页数:7
相关论文
共 14 条
[1]   Hydrogen storage in carbon nanotubes [J].
Cheng, HM ;
Yang, QH ;
Liu, C .
CARBON, 2001, 39 (10) :1447-1454
[2]   Fully sealed, high-brightness carbon-nanotube field-emission display [J].
Choi, WB ;
Chung, DS ;
Kang, JH ;
Kim, HY ;
Jin, YW ;
Han, IT ;
Lee, YH ;
Jung, JE ;
Lee, NS ;
Park, GS ;
Kim, JM .
APPLIED PHYSICS LETTERS, 1999, 75 (20) :3129-3131
[3]   Synthesis optimization and characterization of multiwalled carbon nanotubes [J].
Deck, CP ;
McKee, GSB ;
Vecchio, KS .
JOURNAL OF ELECTRONIC MATERIALS, 2006, 35 (02) :211-223
[4]   Temperature selective growth of carbon nanotubes by chemical vapor deposition [J].
Ducati, C ;
Alexandrou, I ;
Chhowalla, M ;
Amaratunga, GAJ ;
Robertson, J .
JOURNAL OF APPLIED PHYSICS, 2002, 92 (06) :3299-3303
[5]   Water-Assisted Highly Efficient Synthesis of Impurity-Free Single-Walled Carbon Nanotubes [J].
Hata, K ;
Futaba, DN ;
Mizuno, K ;
Namai, T ;
Yumura, M ;
Iijima, S .
SCIENCE, 2004, 306 (5700) :1362-1364
[6]   HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].
IIJIMA, S .
NATURE, 1991, 354 (6348) :56-58
[7]   Pyrolytic synthesis of long strands of large diameter single-walled carbon nanotubes at atmospheric pressure in the absence of sulphur and hydrogen [J].
Lupo, F ;
Rodríguez-Manzo, JA ;
Zamudio, A ;
Elías, AL ;
Kim, YA ;
Hayashi, T ;
Muramatsu, M ;
Kamalakaran, R ;
Terrones, H ;
Endo, M ;
Rühle, M ;
Terrones, M .
CHEMICAL PHYSICS LETTERS, 2005, 410 (4-6) :384-390
[8]   Low-temperature synthesis of high-purity single-walled carbon nanotubes from alcohol [J].
Maruyama, S ;
Kojima, R ;
Miyauchi, Y ;
Chiashi, S ;
Kohno, M .
CHEMICAL PHYSICS LETTERS, 2002, 360 (3-4) :229-234
[9]   Growth of multiwalled carbon nanotubes during the initial stages of aerosol-assisted CCVD [J].
Pinault, M ;
Mayne-L'Hermite, M ;
Reynaud, C ;
Pichot, V ;
Launois, P ;
Ballutaud, D .
CARBON, 2005, 43 (14) :2968-2976
[10]   Carbon nanotubes produced by aerosol pyrolysis: growth mechanisms and post-annealing effects [J].
Pinault, M ;
Mayne-L'Hermite, M ;
Reynaud, C ;
Beyssac, O ;
Rouzaud, JN ;
Clinard, C .
DIAMOND AND RELATED MATERIALS, 2004, 13 (4-8) :1266-1269