Thiadiazole-derived expanded heteroazaporphyrinoids

被引：59

作者：

Islyaikin, MK ^{[1
]}

Danilova, EA

Yagodarova, LD

Rodríguez-Morgade, MS

Torres, T

机构：

[1] Univ Autonoma Madrid, Dept Quim Organ C1, E-28049 Madrid, Spain

[2] Ivanovo State Univ Chem & Technol, Dep Fine Organ Chem, Ivanovo 153460, Russia

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 14期

关键词：

D O I：

10.1021/ol015924l

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Heteroannulenes 1 and 3 containing three subunits of isoindole or pyrrole, respectively, three 1,3,4-thiadiazole moieties, and six aza-bridges have been synthesized by reaction of the corresponding diiminoisoindoline or diiminopyrroline with 2,5-diamino-1,3,4-thiadiazole. These conjugated nonaromatic 30 pi -electron macrocycles coordinate three metal ions within their central cavity and constitute one of the rare examples of expanded heteroazaporphyrinoids.

引用

页码：2153 / 2156

页数：4

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