Electrochemical preparation and characterization of conducting copolymers:: poly(pyrrole-co-indole)

被引：80

作者：

Dhanalakshmi, K ^{[1
]}

Saraswathi, R ^{[1
]}

机构：

[1] Madurai Kamaraj Univ, Dept Mat Sci, Madurai 625021, Tamil Nadu, India

来源：

JOURNAL OF MATERIALS SCIENCE | 2001年 / 36卷 / 17期

关键词：

D O I：

10.1023/A:1017988015634

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Copolymerization of pyrrole and indole was achieved electrochemically in acetonitrile containing lithium perchlorate as supporting electrolyte. The copolymer compositions can be altered by varying the comonomer feed ratios during preparation. The copolymers were characterized by conductivity measurements, cyclic voltammetry, scanning electron microscopy, UV-visible and IR spectroscopic techniques. A possible scheme for the copolymerization mechanism has been suggested. (C) 2001 Kluwer Academic Publishers.

引用

页码：4107 / 4115

页数：9

共 37 条

[1]

[Anonymous], HDB CONDUCTING POLYM

[2] THE ELECTRODEPOSITION OF POLYPYRROLE FILMS FROM AQUEOUS-SOLUTIONS [J].

ASAVAPIRIYANONT, S ;

CHANDLER, GK ;

GUNAWARDENA, GA ;

PLETCHER, D .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 177 (1-2) :229-244

[3] NUCLEATION, GROWTH AND BRANCHING OF POLYANILINE FROM MICROELECTRODE EXPERIMENTS [J].

BADE, K ;

TSAKOVA, V ;

SCHULTZE, JW .

ELECTROCHIMICA ACTA, 1992, 37 (12) :2255-2261

[4]

BARTLETT PN, 1992, B ELECTROCHEM, V8, P208

[5] AN INVESTIGATION OF ELECTROCHEMICALLY AND CHEMICALLY POLYMERIZED INDOLE [J].

BILLAUD, D ;

MAAROUF, EB ;

HANNECART, E .

MATERIALS RESEARCH BULLETIN, 1994, 29 (12) :1239-1246

[6] CHEMICAL OXIDATION AND POLYMERIZATION OF INDOLE [J].

BILLAUD, D ;

MAAROUF, EB ;

HANNECART, E .

SYNTHETIC METALS, 1995, 69 (1-3) :571-572

[7] XPS STUDIES OF COPOLYMERS OF PYRROLE AND N-METHYL-PYRROLE [J].

CHAN, HSO ;

KANG, ET ;

NEOH, KG ;

TAN, KL ;

TAN, BTG ;

LIM, YK .

SYNTHETIC METALS, 1989, 30 (02) :189-197

[8] THE MORPHOLOGY AND CONDUCTIVITY OF POLYPYRROLE POLYURETHANE ALLOY-FILMS [J].

CHIU, HT ;

LIN, JS ;

HUANG, CM .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 1992, 22 (04) :358-363

[9] POLYMERIZATION MECHANISM AND PHYSICOCHEMICAL PROPERTIES OF ELECTROCHEMICALLY PREPARED POLYINDOLE TETRAFLUOROBORATE [J].

CHOI, KM ;

KIM, CY ;

KIM, KH .

JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (09) :3782-3788

[10] POLY(PYRROLE) AS A SUPPORT FOR ELECTROCATALYTIC MATERIALS [J].

CURRAN, D ;

GRIMSHAW, J ;

PERERA, SD .

CHEMICAL SOCIETY REVIEWS, 1991, 20 (03) :391-404

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