A Microporous Hydrogen-Bonded Organic Framework for Highly Selective C2H2/C2H4 Separation at Ambient Temperature

被引:629
作者
He, Yabing [1 ]
Xiang, Shengchang [1 ]
Chen, Banglin [1 ]
机构
[1] Univ Texas San Antonio, Dept Chem, San Antonio, TX 78249 USA
关键词
INFINITE POLYMERIC FRAMEWORKS; MOLECULAR TECTONICS; NETWORKS; ADSORPTION; CRYSTALS; SIEVE; SIZE; CAPACITY; STORAGE; DESIGN;
D O I
10.1021/ja2066016
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first microporous hydrogen-bonded organic framework with permanent porosity and exhibiting extraordinarily highly selective adsorptive separation of C2H2 and C2H4 at ambient temperature has been established.
引用
收藏
页码:14570 / 14573
页数:4
相关论文
共 62 条
[1]   High and Selective CO2 Uptake in a Cobalt Adeninate Metal-Organic Framework Exhibiting Pyrimidine- and Amino-Decorated Pores [J].
An, Jihyun ;
Geib, Steven J. ;
Rosi, Nathaniel L. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (01) :38-+
[2]   Crystal engineering of stacked aromatic columns. Three-dimensional control of the alignment of orthogonal aromatic triads and guest quinones via self-assembly of hydrogen-bonded networks [J].
Aoyama, Y ;
Endo, K ;
Anzai, T ;
Yamaguchi, Y ;
Sawaki, T ;
Kobayashi, K ;
Kanehisa, N ;
Hashimoto, H ;
Kai, Y ;
Masuda, H .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (24) :5562-5571
[3]   Hydrogen-bonded porphyrinic solids: Supramolecular networks of octahydroxy porphyrins [J].
Bhyrappa, P ;
Wilson, SR ;
Suslick, KS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (36) :8492-8502
[4]   Designing permeable molecular crystals that react with external agents to give crystalline products [J].
Brunet, P ;
Demers, E ;
Maris, T ;
Enright, GD ;
Wuest, JD .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (43) :5303-5306
[5]   Molecular tectonics. Porous hydrogen-bonded networks with unprecedented structural integrity [J].
Brunet, P ;
Simard, M ;
Wuest, JD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (11) :2737-2738
[6]   Dramatic tuning of carbon dioxide uptake via metal substitution in a coordination polymer with cylindrical pores [J].
Caskey, Stephen R. ;
Wong-Foy, Antek G. ;
Matzger, Adam J. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (33) :10870-+
[7]   Metal-Organic Frameworks with Functional Pores for Recognition of Small Molecules [J].
Chen, Banglin ;
Xiang, Shengchang ;
Qian, Guodong .
ACCOUNTS OF CHEMICAL RESEARCH, 2010, 43 (08) :1115-1124
[8]   A microporous metal-organic framework for gas-chromatographic separation of alkanes [J].
Chen, BL ;
Liang, CD ;
Yang, J ;
Contreras, DS ;
Clancy, YL ;
Lobkovsky, EB ;
Yaghi, OM ;
Dai, S .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (09) :1390-1393
[9]   Multiroute Synthesis of Porous Anionic Frameworks and Size-Tunable Extraframework Organic Cation-Controlled Gas Sorption Properties [J].
Chen, Shumei ;
Zhang, Jian ;
Wu, Tao ;
Feng, Pingyun ;
Bu, Xianhui .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (44) :16027-+
[10]   A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n [J].
Chui, SSY ;
Lo, SMF ;
Charmant, JPH ;
Orpen, AG ;
Williams, ID .
SCIENCE, 1999, 283 (5405) :1148-1150