Synthesis, characterization, and antifouling potential of functionalized copper nanoparticles

被引:163
作者
Anyaogu, Kelechi C. [1 ]
Fedorov, Andrei V. [1 ]
Neckers, Douglas C. [1 ]
机构
[1] Bowling Green State Univ, Ctr Photochem Sci, Bowling Green, OH 43403 USA
关键词
D O I
10.1021/la800102f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis, characterization, and antimicrobial properties of functionalized copper nanoparticle/polymer composites are reported. Copper nanoparticles (Cu NPs) are stabilized by surface attachment of the acrylic functionality that can be copolymerized with other acrylic monomers, thus, becoming an integral part of the polymer backbone. Biological experiments show that Cu NP/polymer composites exhibit antimicrobial activity similar to that of conventional copper-based biocides. Atomic absorption spectroscopy shows the smallest amount of copper ions leaching from chemically bound acrylated Cu NPs compared to the nonfunctionalized biocides. These composites have a strong potential for use in antibacterial or marine antifouling coatings.
引用
收藏
页码:4340 / 4346
页数:7
相关论文
共 45 条
[1]   SIMPLE CONDITIONS FOR GROWTH OF UNICELLULAR BLUE-GREEN ALGAE ON PLATES [J].
ALLEN, MM .
JOURNAL OF PHYCOLOGY, 1968, 4 (01) :1-&
[2]  
Anderson C., 2003, J. Mar. Des. Oper, VB4, P11
[3]   Three-dimensional self-assembled monolayer (3D SAM) of n-alkanethiols on copper nanoclusters [J].
Ang, TP ;
Wee, TSA ;
Chin, WS .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (30) :11001-11010
[4]  
ANTONIETTA ZM, 1996, J INORG BIOCHEM, V35, P291
[5]   Formation of Cu and Cu2O nanoparticles by variation of the surface ligand:: Preparation, structure, and insulating-to-metallic transition [J].
Aslam, M ;
Gopakumar, G ;
Shoba, TL ;
Mulla, IS ;
Vijayamohanan, K ;
Kulkarni, SK ;
Urban, J ;
Vogel, W .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2002, 255 (01) :79-90
[6]   Copper toxicity towards Saccharomyces cerevisiae: Dependence on plasma membrane fatty acid composition [J].
Avery, SV ;
Howlett, NG ;
Radice, S .
APPLIED AND ENVIRONMENTAL MICROBIOLOGY, 1996, 62 (11) :3960-3966
[7]   Synthesis and biological activity of photopolymerizable derivatives of glyphosate [J].
Bogdanova, Aneta ;
Piunova, Victoria ;
Berger, Daniel ;
Fedorov, Andrei V. ;
Neckers, Douglas C. .
BIOMACROMOLECULES, 2007, 8 (02) :439-447
[8]   SYNTHESIS AND REACTIONS OF FUNCTIONALIZED GOLD NANOPARTICLES [J].
BRUST, M ;
FINK, J ;
BETHELL, D ;
SCHIFFRIN, DJ ;
KIELY, C .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (16) :1655-1656
[9]   Photopolymerization of gold nanoparticles: Size-related charge separation and emission [J].
Cai, Xichen ;
Anyaogu, Kelechi C. ;
Neckers, Douglas C. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (37) :11324-+
[10]   The use of CTAB to control the size of copper nanoparticles and the concentration of alkylthiols on their surfaces [J].
Chen, L ;
Zhang, DJ ;
Chen, JM ;
Zhou, HD ;
Wan, HQ .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2006, 415 (1-2) :156-161