Aggregation/deaggregation processes in vanadium(II) carboxylate chemistry

被引：11

作者：

Bonitatebus, PJ ^{[1
]}

Armstrong, WH ^{[1
]}

机构：

[1] Boston Coll, Dept Chem, Merkert Chem Ctr, Chestnut Hill, MA 02167 USA

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 01期

关键词：

D O I：

10.1039/a806105j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions of potassium tris(3,5-dimethylpyrazolyl)borate (KTpb(Me2)) with the low-valent mixed-metal complex [(thf)(3)V(mu-Cl)(mu-tfa)(2)V(thf)(3)] [ZnCl3(thf)] resulted first in ZnCl+ abstraction and tetramer formation, then in asymmetric binuclear product formation through ligand substitution.

引用

页码：55 / 56

页数：2

共 12 条

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