An efficient and selective method for preparing glycosyl sulfoxides by oxidizing glycosyl sulfides with OXONE or t-BuOOH on SiO2

被引：23

作者：

Chen, MY

Patkar, LN

Chen, HT

Lin, CC

机构：

[1] Acad Sinica, Inst Chem, Taipei 115, Taiwan

[2] Taipei Nursing Coll, Dept Gen Educ, Taipei 112, Taiwan

来源：

CARBOHYDRATE RESEARCH | 2003年 / 338卷 / 12期

关键词：

OXONE; t-BuOOH; glycosyl sulfoxide; oxidation; silica gel support;

D O I：

10.1016/S0008-6215(03)00164-2

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Silica gel adsorbed with OXONE or t-BuOOH was used as a mild oxidant to selectively oxidize glycosyl sulfides to corresponding sulfoxides in good yields and without sulfones formation. This method was also found compatible with various other functional groups in the glycosides. (C) 2003 Elsevier Science Ltd. All rights reserved.

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页码：1327 / 1332

页数：6

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