Synthesis and structure of [Tl(C6F5)(2)Cl{Au(C6F5)(3)(PPh(2)CH(2)PPh(2)(O))}(2)]

被引：8

作者：

Alvarez, B

Fernandez, EJ

Gimeno, MC

Jones, PG

Laguna, A

Laguna, M

LopezdeLuzuriaga, JM

机构：

[1] UNIV ZARAGOZA, CSIC, INST CIENCIA MAT ARAGON, DEPT QUIM INORGAN, E-50009 ZARAGOZA, SPAIN

[2] UNIV LA RIOJA, DEPT QUIM, E-26001 LOGRONO, SPAIN

[3] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG, INST ANORGAN & ANALYT CHEM, D-38023 BRAUNSCHWEIG, GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 525卷 / 1-2期

关键词：

gold; thallium; crystal structure; pentafluorophenyl;

D O I：

10.1016/S0022-328X(96)06506-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two trinuclear gold-thallium-gold complexes, {Tl(C6F5)(2)X{Au(C6F5)(3)(PPH(2)CH(2)PPh(2)CH(2)PPh(2)(O))}(2)} (X = C6F5, Cl), have been synthesised by reaction of [Au(C6F5)(3)(PPh(2)(O))] with [Tl(C6F5)(2)Cl] or [Tl(C6F5)(3)(diox)], in which the phosphine oxide moiety coordinates to thallium; the crystal structure of the former product has been established by X-ray diffraction.

引用

页码：109 / 113

页数：5

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