Variable and stereoselective synthesis of azasugar analogues by a ruthenium-catalyzed ring rearrangement

被引：46

作者：

Voigtmann, U ^{[1
]}

Blechert, S ^{[1
]}

机构：

[1] Tech Univ Berlin, Inst Organ Chem, D-10623 Berlin, Germany

来源：

ORGANIC LETTERS | 2000年 / 2卷 / 25期

关键词：

D O I：

10.1021/ol000188r

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel ruthenium catalyzed ring opening/ring closing tandem metathesis reaction with a catalytic transfer of stereocenters from a ring to an olefinic chain is described. This ring rearrangement serves as the key step in the stereoselective synthesis of the new azasugar analogues 1 and 2.

引用

页码：3971 / 3974

页数：4

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