Synthesis of crown-ester-bipyridines and crown-ester-viologens

被引：10

作者：

Bossmann, SH

Dürr, H

Pokhrel, MR

机构：

[1] Kansas State Univ, Dept Chem, Manhattan, KS 66506 USA

[2] Univ Saarland, Dept Chem, Sect Organ Chem, D-66041 Saarbrucken, Germany

[3] Tribhuvan Univ, Cent Dept Chem, Kathmandu, Nepal

来源：

SYNTHESIS-STUTTGART | 2005年 / 06期

关键词：

alkylations; bipyridines; esters; nickel(0); viologens;

D O I：

10.1055/s-2005-861829

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Six novel 4,4'-bipyridine-crown-esters, derived from [4,4']bipyridinyl-3,3'-dicarboxylic acid, [4,4']bipyridinyl-2,2'-dicarboxylic acid and [4,4']bipyridinyl-2,2',6,6'-tetra-carboxylic acid were synthesized employing a procedure closely related to the 'cesium carbonate method'. The 4,4'-bipyridine-crown-esters differ in their substitution positions of the aromatic bipyridine-units, as well as in the geometric extensions of their crown-ester moieties. Addition of 1,3-propane sultone to the 4,4'-bipyridine-crown-esters resulted in five novel propanesultonated 4,4'-bipyridine-crown-esteiviologens.

引用

页码：907 / 914

页数：8

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