Optimal design of an in situ Fe(II) barrier: Transport limited reoxidation

被引:18
作者
Chilakapati, A
Williams, M
Yabusaki, S
Cole, C
Szecsody, J
机构
[1] Xerago LLC, San Diego, CA 92101 USA
[2] Pacific NW Lab, Richland, WA 99352 USA
关键词
D O I
10.1021/es000920h
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Harmful contaminants such as Cr(VI) and TCE can be removed from groundwater by reactions with chemically reduced subsurface sediments. This paper studies the optimal selection of the number of wells, the injection rate, and the number of regenerations of a large-scale Fe(II) barrier for Cr(VI) remediation at Hanford, WA. The process model consists of two parts: (a) the creation of the Fe(II) barrier by the injection of a dithionite reagent and (b) the reoxidation of the barrier by Cr(VI) and oxygen in the invading groundwater. The solution to the process model is used to develop the total cost as a function of the design variables. This cost model is applied to the Cr(VI) contamination at Hanford to obtain the optimal design configuration and its sensitivity to cost and process uncertainties.
引用
收藏
页码:5215 / 5221
页数:7
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