Electron transport in conjugated metallopolymers

被引：15

作者：

Cameron, CG ^{[1
]}

MacLean, BJ ^{[1
]}

Pickup, PG ^{[1
]}

机构：

[1] Mem Univ Newfoundland, Dept Chem, St Johns, NF A1B 3X7, Canada

来源：

MACROMOLECULAR SYMPOSIA | 2003年 / 196卷

关键词：

charge transport; conjugated polymers; electrochemistry; metal-polymer complexes; superexchange;

D O I：

10.1002/masy.200390157

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Superexchange interactions between metal centers coordinated to various conjugated polymer backbones have been shown to enhance the rate of electron transport through the polymer. Results for Ru and Os bipyridine moieties complexed to polybenzimidzoles and poly(bithiophene-co-bithiazole)s are reviewed. The evidence for superexchange mediated electron transport, and the factors that influence the rate of electron hopping between metal centers, are discussed.

引用

页码：165 / 171

页数：7

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