A resonant two-color photoionization threshold determination of the ionization energy of the LiOLi molecule

被引:7
作者
Bellert, D [1 ]
Breckenridge, WH [1 ]
机构
[1] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA
关键词
D O I
10.1016/S0009-2614(01)00190-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
By measuring the ionization thresholds for several R2PI (resonance-enhanced two-photon ionization spectroscopy) rovibronic transitions from (LiOLi)-Li-7-O-16-Li-7[(l)Sigma (+)(g)(0, 0, 0)] to (LiOLi)-Li-7-O-16-Li-7[B-1(l)] have determined the ionization energy of the (LiOLi)-Li-7-O-16-Li-7 molecule: 50907 +/- 4 cm(-1) (6.3117 +/- 0.0005 eV). This value is similar to, but much more accurate than, previous experimental and ab initio estimates. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:103 / 106
页数:4
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