Solvent vapor-induced nanowire formation in poly(3-hexylthiophene) thin films

被引：129

作者：

Kim, DH ^{[1
]}

Park, YD ^{[1
]}

Jang, Y ^{[1
]}

Kim, S ^{[1
]}

Cho, K ^{[1
]}

机构：

[1] Pohang Univ Sci & Technol, Dept Chem Engn, Pohang 790784, South Korea

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2005年 / 26卷 / 10期

关键词：

nanowire; organic field-effect transistors; polythiophene; self-assembly; solvent vapor;

D O I：

10.1002/marc.200400647

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Nanowire lengths and length-to-width aspect ratios in regioregular poly(3-hexylthiophene) (P3HT) were simply controlled through changes in the solvent vapor pressure during solidification. It is demonstrated that the nanowires grew by rod-to-rod association, in which the molecular long axis of the P3HT chains appeared to be well-oriented parallel to the silicon substrate (Si/SiOx). The formation of the nanowires took place by one dimensional self-assembly, governed by pi-pi stacking of the P3HT units.

引用

页码：834 / 839

页数：6

共 41 条

[1] Structural anisotropy of poly(alkylthiophene) films [J].

Aasmundtveit, KE ;

Samuelsen, EJ ;

Guldstein, M ;

Steinsland, C ;

Flornes, O ;

Fagermo, C ;

Seeberg, TM ;

Pettersson, LAA ;

Inganäs, O ;

Feidenhans'l, R ;

Ferrer, S .

MACROMOLECULES, 2000, 33 (08) :3120-3127

[2] Field-effect mobility of charge carriers in blends of regioregular poly(3-alkylthiophene)s [J].

Babel, A ;

Jenekhe, SA .

JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (08) :1749-1754

[3] Soluble and processable regioregular poly(3-hexylthiophene) for thin film field-effect transistor applications with high mobility [J].

Bao, Z ;

Dodabalapur, A ;

Lovinger, AJ .

APPLIED PHYSICS LETTERS, 1996, 69 (26) :4108-4110

[4] OLIGOTHIOPHENES - YET LONGER - SYNTHESIS, CHARACTERIZATION, AND SCANNING-TUNNELING-MICROSCOPY IMAGES OF HOMOLOGOUS, ISOMERICALLY PURE OLIGO(ALKYLTHIOPHENE)S [J].

BAUERLE, P ;

FISCHER, T ;

BIDLINGMEIER, B ;

STABEL, A ;

RABE, JP .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (03) :303-307

[5]

Bjornholm T, 1999, ADV MATER, V11, P1218, DOI 10.1002/(SICI)1521-4095(199910)11:14<1218::AID-ADMA1218>3.0.CO

[6]

2-G

[7] Cyclodextrin-threaded conjugated polyrotaxanes as insulated molecular wires with reduced interstrand interactions [J].

Cacialli, F ;

Wilson, JS ;

Michels, JJ ;

Daniel, C ;

Silva, C ;

Friend, RH ;

Severin, N ;

Samorì, P ;

Rabe, JP ;

O'Connell, MJ ;

Taylor, PN ;

Anderson, HL .

NATURE MATERIALS, 2002, 1 (03) :160-164

[8] REGIOCONTROLLED SYNTHESIS OF POLY(3-ALKYLTHIOPHENES) MEDIATED BY RIEKE ZINC - THEIR CHARACTERIZATION AND SOLID-STATE PROPERTIES [J].

CHEN, TA ;

WU, XM ;

RIEKE, RD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (01) :233-244

[9]

Dimitrakopoulos CD, 2002, ADV MATER, V14, P99, DOI 10.1002/1521-4095(20020116)14:2<99::AID-ADMA99>3.0.CO

[10]

2-9

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