Air-stable racemization catalyst for dynamic kinetic resolution of secondary alcohols at room temperature

被引：77

作者：

Kim, N ^{[1
]}

Ko, SB ^{[1
]}

Kwon, MS ^{[1
]}

Kim, MJ ^{[1
]}

Park, J ^{[1
]}

机构：

[1] Pohang Univ Sci & Technol, POSTECH, Div Mol & Life Sci, Dept Chem,Natl Res Lab Chirotechnol, Pohang 790784, South Korea

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 20期

关键词：

D O I：

10.1021/ol051889x

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

graph A novel racemization catalyst was synthesized for the dynamic kinetic resolution (DKR) of alcohols with a lipase at room temperature in the air. Furthermore, a polymer-supported derivative was also synthesized and tested as a recyclable catalyst for the aerobic DKR of alcohols.

引用

页码：4523 / 4526

页数：4

共 21 条

[1] Dynamic resolutions in asymmetric synthesis [J].