The atmospheric chemistry of alkoxy radicals

被引：323

作者：

Orlando, JJ

Tyndall, GS

Wallington, TJ

机构：

[1] Natl Ctr Atmospher Res, Div Atmospher Chem, Boulder, CO 80307 USA

[2] Ford Motor Co, Ford Res Lab, Dearborn, MI 48121 USA

来源：

CHEMICAL REVIEWS | 2003年 / 103卷 / 12期

关键词：

D O I：

10.1021/cr020527p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The importance of alkoxy radicals in the atmospheric chemistry was discussed. Absolute rates and temperature dependences of major atmospheric reactions, unimolecular dissociation and reaction with oxygen, were also obtained and studied in the case of the nonsubstituted alkoxy radicals. The direct studies of alkoxy radicals was carried out using pulsed laser photolysis to generate the alkoxy radicals, and pulsed laser-induced fluorescence for their detection. Direct detection of alkoxy radical isomerization reaction and of the effects of chemical activation proved to be of great importance.

引用

页码：4657 / 4689

页数：33

共 229 条

[1]

Aschmann S. M, 2002, J GEOPHYS RES, V107

[2]

Aschmann SM, 1999, INT J CHEM KINET, V31, P501, DOI 10.1002/(SICI)1097-4601(1999)31:7<501::AID-KIN5>3.3.CO

[3]

2-8

[4] Formation of β-hydroxycarbonyls from the OH radical-initiated reactions of selected alkenes [J].