Chemistry of η5-fullerene metal complexes

被引：55

作者：

Nakamura, E ^{[1
]}

Sawamura, M ^{[1
]}

机构：

[1] Univ Tokyo, Dept Chem, Tokyo 1130033, Japan

来源：

PURE AND APPLIED CHEMISTRY | 2001年 / 73卷 / 02期

关键词：

D O I：

10.1351/pac200173020355

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of [60]fullerene with an organocopper reagent converts one of the pen tagons of the fullerene into cyclopentadienyl anion through addition of five organic groups on every peripheral carbon atom surrounding the pentagon. Similar treatment of [70]fullerene afforded indenyl anion through regioselective tri-addition of the organic group. These anionic moieties strongly interact with the remainder of the fullerene pi -system, and provide unique opportunity for exploration of organometallic chemistry of a new class of metal cyclopentadienides.

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页码：355 / 359

页数：5

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