Hydrolysis of sodium borohydride with steam

被引：78

作者：

Marrero-Alfonso, Eyma Y. ^{[1
]}

Gray, Joshua R. ^{[1
]}

Davis, Thomas A. ^{[1
]}

Matthews, Michael A. ^{[1
]}

机构：

[1] Univ S Carolina, Dept Chem Engn, Swearingen Engn Ctr, Columbia, SC 29208 USA

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2007年 / 32卷 / 18期

关键词：

sodium borohydride; hydrolysis; steam; chemical hydrides;

D O I：

10.1016/j.ijhydene.2007.07.066

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction of sodium borohydride with steam produces hydrogen gas and a hydrated solid. Unlike the reaction in liquid water, up to 95% yield of hydrogen is obtained with pure steam without a catalyst. Liquid promoters (methanol and acetic acid) at concentrations of 1 mol% do not enhance the reaction rate, although acetic acid improves the hydrogen yield slightly. (c) 2007 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.

引用

页码：4717 / 4722

页数：6

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