Growing semiconductor nanocrystals directly in a conducting polymer

被引:19
作者
Watt, A [1 ]
Rubinsztein-Dunlop, H
Meredith, P
机构
[1] Univ Queensland, Soft Condensed Matter Phys Grp, Brisbane, Qld, Australia
[2] Univ Queensland, Sch Phys Sci, Ctr Biophoton & Laser Sci, Brisbane, Qld, Australia
基金
澳大利亚研究理事会;
关键词
nanocomposites; optical materials and properties; polymers; solar energy materials;
D O I
10.1016/j.matlet.2005.05.013
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We describe a single step method to synthesise lead sulphide (PbS) nanocrystals directly in the conjugated polymer poly (2-methoxy-5-(2'-ethyl-hexyloxy)-p-phenylene vinylene) (MEH-PPV). This method allows size control of the nanocrystal via co-solvent ratios. We find good agreement between nanocrystal sizes determined by transmission electron microscopy and sizes theoretically determined from the absorption edge of the nanocrystals. Finally we show that this synthesis technique is not restricted to MEH-PPV and demonstrate that nanocrystals can be grown in Poly(3-hexylthiophene-2,5-diyl) (P3HT). (C) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:3033 / 3036
页数:4
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