Facile regiocontrolled synthesis of trialkyl-substituted pyrazines

被引：19

作者：

Elmaaty, TA ^{[1
]}

Castle, LW ^{[1
]}

机构：

[1] Idaho State Univ, Dept Chem, Pocatello, ID 83209 USA

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 24期

关键词：

D O I：

10.1021/ol0523751

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

alpha-Nitro ketones can be transformed selectively into trialkyl-substituted pyrazines via reaction with a-amino ketones using octyl viologen as an electron-transfer reagent. The new synthetic method, and the optimal reaction conditions that allow for the regiochemical control, are described.

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页码：5529 / 5530

页数：2

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