The controlled evolution of a polymer single crystal

被引:99
作者
Liu, XG
Zhang, Y
Goswami, DK
Okasinski, JS
Salaita, K
Sun, P
Bedzyk, MJ
Mirkin, CA [1 ]
机构
[1] Northwestern Univ, Dept Mat Sci & Engn, Inst Nanotechnol, Evanston, IL 60208 USA
[2] Northwestern Univ, Nanoscale Sci & Engn Ctr, Evanston, IL 60208 USA
[3] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
关键词
D O I
10.1126/science.1109487
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
We present a method for controlling the initiation and kinetics of polymer crystal growth using dip-pen nanolithography and an atomic force microscope tip coated with poly-DL-lysine hydrobromide. Triangular prisms of the polymer epitaxially grow on freshly cleaved mica substrates, and their in-plane and out-of-plane growth rates can be controlled by raster scanning the coated tip across the substrate. Atomic force microscope images were concomitantly recorded, providing a set of photographic images of the process as it spans the nanometer-to micrometer-length scales as a function of environmental conditions.
引用
收藏
页码:1763 / 1766
页数:4
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