Archaea;
Thermococcus sp;
novel glycerol diether lipid;
NMR;
mass spectrometry;
D O I:
10.1016/S0040-4039(01)00305-7
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
The lipids of a deep-sea hydrothermal vent arch ae on, Thermococcus S 557, were isolated, purified and structurally determined. Based on acid methanolysis and spectroscopic studies, the polar lipids were shown to comprise diphytanyl glycerol and dibiphytanyl diglycerol, typical membrane lipids of Arch aea. From the neutral lipids, 2,3-di-O-dihydro-14,15-geranylgeranyl glycerol was isolated. This novel ether lipid is, very likely, a close intermediate in the biosynthesis of diphytanyl glycerol diether in Arch aea. (C) 2001 Elsevier Science Ltd. All rights reserved.