Minimization of noise in spectral data

被引:9
作者
Iwata, T
Koshoubu, J
机构
[1] JASCO Tech. Res. Labs. Corporation, Hachioji-shi, Tokyo 192, 2097-2, Ishikawa-cho
关键词
singular value decomposition; noise minimization; smoothing; data processing; computer application;
D O I
10.1366/0003702963905637
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
We have developed a novel noise-minimization method that is applicable to all kinds of spectral data, which introduces little distortion in the signal waveform. It is based on the singular value decomposition of a matrix and is an advanced version of the conventional method for minimizing the background noise from a line spectrum, the details of which we reported in a previous paper [Appl. Spectrosc, 48, 1453 (1994).]. In order to cope with a continuum spectrum, we have calculated a difference spectrum between an observed spectrum and a smoothed one. After minimizing noise components from the difference spectrum by the use of the previous method, we add it to the smoothed spectrum, We also propose a method for reducing the computation time by introducing a data-division technique, Noise minimization for an infrared absorption spectrum of polystyrene is shown.
引用
收藏
页码:747 / 752
页数:6
相关论文
共 7 条
[1]   ACCOUNTING FOR IMPURITIES IN SPECTROSCOPIC MULTICOMPONENT ANALYSIS USING FOURIER VECTORS [J].
BROWN, CW ;
BUMP, EA ;
OBREMSKI, RJ .
APPLIED SPECTROSCOPY, 1986, 40 (07) :1023-1031
[2]   INFRARED QUANTITATIVE-ANALYSIS IN THE FOURIER DOMAIN - PROCESSING VECTOR REPRESENTATIONS [J].
BROWN, CW ;
OBREMSKI, RJ ;
ANDERSON, P .
APPLIED SPECTROSCOPY, 1986, 40 (06) :734-742
[3]   PARTIAL LEAST-SQUARES REGRESSION - A TUTORIAL [J].
GELADI, P ;
KOWALSKI, BR .
ANALYTICA CHIMICA ACTA, 1986, 185 :1-17
[4]   NOISE-REDUCTION VIA FACTOR-ANALYSIS IN FT-IR SPECTRA [J].
GILLETTE, PC ;
KOENIG, JL .
APPLIED SPECTROSCOPY, 1982, 36 (05) :535-539
[5]   NEW METHOD TO ELIMINATE THE BACKGROUND-NOISE FROM A LINE SPECTRUM [J].
IWATA, T ;
KOSHOUBU, J .
APPLIED SPECTROSCOPY, 1994, 48 (12) :1453-1456
[6]   ADAPTIVE SMOOTHING OF SPECTROSCOPIC DATA BY A LINEAR MEAN-SQUARE ESTIMATION [J].
KAWATA, S ;
MINAMI, S .
APPLIED SPECTROSCOPY, 1984, 38 (01) :49-58
[7]   SMOOTHING + DIFFERENTIATION OF DATA BY SIMPLIFIED LEAST SQUARES PROCEDURES [J].
SAVITZKY, A ;
GOLAY, MJE .
ANALYTICAL CHEMISTRY, 1964, 36 (08) :1627-&