A chiral anisotropic reagent for determination of the absolute configuration of a primary amino compound

被引：24

作者：

Harada, K ^{[1
]}

Shimizu, Y ^{[1
]}

Fujii, K ^{[1
]}

机构：

[1] Meijo Univ, Fac Pharm, Tempa Ku, Nagoya, Aichi 4688503, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 34期

关键词：

D O I：

10.1016/S0040-4039(98)01286-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A chiral anisotropic reagent, 1-fluoro-2,4-dinitrophenyl-5-(R,S)-phenylethylamine ((R,S)-FDPEA, 2), was developed for determination of the absolute configuration of the alpha-carbon of primary amino compounds. This reagent has advantages over conventional reagents in terms of reactivity, reliability and effectiveness, and was successfully applied to a peptide, microginin, produced by cyanobacteria. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：6245 / 6248

页数：4

共 7 条

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