Real-time observation of ground state proton transfer: a model study

被引：10

作者：

Arasaki, Y

Yamazaki, K

Varella, MTD

Takatsuka, K ^{[1
]}

机构：

[1] Univ Tokyo, Dept Basic Sci, Grad Sch Arts & Sci, Tokyo 1538902, Japan

[2] Univ Estadual Campinas, UNICAMP, Inst Fis Gleb Wataghin, BR-13083970 Campinas, SP, Brazil

来源：

CHEMICAL PHYSICS | 2005年 / 311卷 / 03期

基金：

巴西圣保罗研究基金会;

关键词：

D O I：

10.1016/j.chemphys.2004.10.043

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We propose a femtosecond dump-probe photoelectron spectroscopy scheme for the real-time observation of ground state proton transfer. Feasibility of such a scheme is investigated with quantum wavepacket dynamics on a model potential. Formation of a proton transfer wavepacket by dumping from an eigenstate or from a delocalized mixture of eigenstates is discussed. Characteristic features of proton transfer observed in the time-dependent ion signal and photoelectron kinetic energy spectra are shown, along with a method of extracting the signals from a background unrelated to proton transfer. (c) 2004 Elsevier B.V. All rights reserved.

引用

收藏

页码：255 / 268

页数：14

相关论文

共 75 条

[1] Femtosecond energy- and angle-resolved photoelectron spectra [J].

Arasaki, Y ;

Takatsuka, K ;

Wang, KH ;

McKoy, V .

CHEMICAL PHYSICS LETTERS, 1999, 302 (5-6) :363-374

[2] Pump-probe photoionization study of the passage and bifurcation of a quantum wave packet across an avoided crossing [J].

Arasaki, Y ;

Takatsuka, K ;

Wang, KH ;

McKoy, V .

PHYSICAL REVIEW LETTERS, 2003, 90 (24) :4

[3] Femtosecond energy- and angle-resolved photoelectron spectroscopy [J].

Arasaki, Y ;

Takatsuka, K ;

Wang, KH ;

McKoy, V .

JOURNAL OF CHEMICAL PHYSICS, 2000, 112 (20) :8871-8884

[4] Studies of electron transfer in NaI with pump-probe femtosecond photoelectron spectroscopy [J].

Arasaki, Y ;

Takatsuka, K ;

Wang, KH ;

McKoy, V .

JOURNAL OF CHEMICAL PHYSICS, 2003, 119 (15) :7913-7923

[5] Detection of the tunneling-rotation transitions of malonaldehyde in the submillimeter-wave region [J].

Baba, T ;

Tanaka, T ;

Morino, I ;

Yamada, KMT ;

Tanaka, K .

JOURNAL OF CHEMICAL PHYSICS, 1999, 110 (09) :4131-4133

[6] MICROWAVE SPECTROSCOPIC STUDY OF MALONALDEHYDE (3-HYDROXY-2-PROPENAL) .2. STRUCTURE, DIPOLE-MOMENT, AND TUNNELING [J].

BAUGHCUM, SL ;

DUERST, RW ;

ROWE, WF ;

SMITH, Z ;

WILSON, EB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (21) :6296-6303

[7]

Bountis T., 1992, PROTON TRANSFER HYDR

[8]

Brumer P., 2001, Phys. Rev. A, V65, DOI DOI 10.1103/PHYSREVA.65.015401

[9] Vibrational coherence in ultrafast excited state proton transfer [J].

Chudoba, C ;

Riedle, E ;

Pfeiffer, M ;

Elsaesser, T .

CHEMICAL PHYSICS LETTERS, 1996, 263 (05) :622-628

[10] Ultrafast excited-state proton transfer of 2-(2′-hydroxyphenyl)benzothiazole:: Theoretical analysis of the skeletal deformations and the active vibrational modes [J].

de Vivie-Riedle, R ;

De Waele, V ;

Kurtz, L ;

Riedle, E .

JOURNAL OF PHYSICAL CHEMISTRY A, 2003, 107 (49) :10591-10599

← 1 2 3 4 5 6 7 8 →