Solvent-Annealed Crystalline Squaraine: PC70BM (1:6) Solar Cells

被引：236

作者：

Wei, Guodan ^{[1
]}

Wang, Siyi ^{[2
]}

Sun, Kai ^{[1
]}

Thompson, Mark E. ^{[2
]}

Forrest, Stephen R. ^{[1
,3
,4
]}

机构：

[1] Univ Michigan, Dept Mat Sci & Engn, Ann Arbor, MI 48109 USA

[2] Univ So Calif, Dept Chem, Los Angeles, CA 90089 USA

[3] Univ Michigan, Dept Elect Engn & Comp Sci, Ann Arbor, MI 48109 USA

[4] Univ Michigan, Dept Phys, Ann Arbor, MI 48109 USA

来源：

ADVANCED ENERGY MATERIALS | 2011年 / 1卷 / 02期

关键词：

NANOSCALE PHASE-SEPARATION; PHOTOVOLTAIC CELLS; SELF-ORGANIZATION; EFFICIENT; POLYMER; MORPHOLOGY; DIFFUSION;

D O I：

10.1002/aenm.201100045

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

It is demonstrated that squaraine:PC70BM blends can result in solar cells with high efficiency and fill factor when the nano-structure scale is increased to lead to conduction of photogenerated carriers to the electrodes. Morphological control occurs by a combination of thermal and solvent annealing of these small molecule, solution-processed bulk heterojunction cells. Peak efficiencies of a population of devices is 5.2% at fill factors of 0.5 are achieved under optimized conditions. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：184 / 187

页数：4

共 23 条

[1] Morphology evolution via self-organization and lateral and vertical diffusion in polymer: fullerene solar cell blends [J].

Campoy-Quiles, Mariano ;

Ferenczi, Toby ;

Agostinelli, Tiziano ;

Etchegoin, Pablo G. ;

Kim, Youngkyoo ;

Anthopoulos, Thomas D. ;

Stavrinou, Paul N. ;

Bradley, Donal D. C. ;

Nelson, Jenny .

NATURE MATERIALS, 2008, 7 (02) :158-164

[2] Charge Photogeneration in Low Band Gap Polyselenophene/Fullerene Blend Films [J].

Clarke, Tracey M. ;

Ballantyne, Amy M. ;

Tierney, Steve ;

Heeney, Martin ;

Duffy, Warren ;

McCulloch, Iain ;

Nelson, Jenny ;

Durrant, James R. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (17) :8068-8075

[3] Correlation between structural and optical properties of composite polymer/fullerene films for organic solar cells [J].

Erb, T ;

Zhokhavets, U ;

Gobsch, G ;

Raleva, S ;

Stühn, B ;

Schilinsky, P ;

Waldauf, C ;

Brabec, CJ .

ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (07) :1193-1196

[4] The limits to organic photovoltaic cell efficiency [J].

Forrest, SR .

MRS BULLETIN, 2005, 30 (01) :28-32

[5] Morphology of polymer/fullerene bulk heterojunction solar cells [J].

Hoppe, H ;

Sariciftci, NS .

JOURNAL OF MATERIALS CHEMISTRY, 2006, 16 (01) :45-61

[6] Improved Performance of Polymer Bulk Heterojunction Solar Cells Through the Reduction of Phase Separation via Solvent Additives [J].

Hoven, Corey V. ;

Dang, Xuan-Dung ;

Coffin, Robert C. ;

Peet, Jeff ;

Nguyen, Thuc-Quyen ;

Bazan, Guillermo C. .

ADVANCED MATERIALS, 2010, 22 (08) :E63-+

[7] Poly(3-hexylthiophene) Nanorods with Aligned Chain Orientation for Organic Photovoltaics [J].

Kim, Jong Soo ;

Park, Yunmin ;

Lee, Dong Yun ;

Lee, Ji Hwang ;

Park, Jong Hwan ;

Kim, Jin Kon ;

Cho, Kilwon .

ADVANCED FUNCTIONAL MATERIALS, 2010, 20 (04) :540-545

[8] High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends [J].

Li, G ;

Shrotriya, V ;

Huang, JS ;

Yao, Y ;

Moriarty, T ;

Emery, K ;

Yang, Y .

NATURE MATERIALS, 2005, 4 (11) :864-868

[9] Relationship between Crystalline Order and Exciton Diffusion Length in Molecular Organic Semiconductors [J].

Lunt, Richard R. ;

Benziger, Jay B. ;

Forrest, Stephen R. .

ADVANCED MATERIALS, 2010, 22 (11) :1233-+

[10] Thermally stable, efficient polymer solar cells with nanoscale control of the interpenetrating network morphology [J].

Ma, WL ;

Yang, CY ;

Gong, X ;

Lee, K ;

Heeger, AJ .

ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (10) :1617-1622

← 1 2 3 →