FeP Nanoparticles Film Grown on Carbon Cloth: An Ultrahighly Active 3D Hydrogen Evolution Cathode in Both Acidic and Neutral Solutions

被引：171

作者：

Tian, Jingqi ^{[1
,2
]}

Liu, Qian ^{[1
]}

Liang, Yanhui ^{[1
]}

Xing, Zhicai ^{[1
]}

Asiri, Abdullah M. ^{[3
,4
]}

Sun, Xuping ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Jilin, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

[3] King Abdulaziz Univ, Fac Sci, Dept Chem, Jeddah 21589, Saudi Arabia

[4] King Abdulaziz Univ, Ctr Excellence Adv Mat Res, Jeddah 21589, Saudi Arabia

来源：

ACS APPLIED MATERIALS & INTERFACES | 2014年 / 6卷 / 23期

基金：

中国国家自然科学基金;

关键词：

FeP nanoparticles; 3D hydrogen evolution cathode; ultrahigh activity; water splitting; acidic and neutral solutions; GENERATING HYDROGEN; METAL ELECTROCATALYSTS; GRAPHENE SHEETS; NANOWIRE ARRAYS; FIBER PAPER; EFFICIENT; PHOSPHIDE; CATALYSTS; WATER;

D O I：

10.1021/am5064684

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

In this Letter, we demonstrate the direct growth of FeP nanoparticles film on carbon cloth (FeP/CC) through low-temperature phosphidation of its Fe3O4/CC precursor. Remarkably, when used as an integrated 3D hydrogen evolution cathode, this FeP/CC electrode exhibits ultrahigh catalytic activity comparable to commercial Pt/C and good stability in acidic media. This electrode also performs well in neutral solutions. This work offers us the most cost-effective and active 3D cathode toward electrochemical water splitting for large-scale hydrogen fuel production.

引用

页码：20579 / 20584

页数：6

共 30 条

[1] Mixed Close-Packed Cobalt Molybdenum Nitrides as Non-noble Metal Electrocatalysts for the Hydrogen Evolution Reaction [J].

Cao, Bingfei ;

Veith, Gabriel M. ;

Neuefeind, Joerg C. ;

Adzic, Radoslav R. ;

Khalifah, Peter G. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (51) :19186-19192

[2] Nanoscaled Metal Borides and Phosphides: Recent Developments and Perspectives [J].

Carenco, Sophie ;

Portehault, David ;

Boissiere, Cedric ;

Mezailles, Nicolas ;

Sanchez, Clement .

CHEMICAL REVIEWS, 2013, 113 (10) :7981-8065

[3] Powering the planet with solar fuel (vol 1, pg 7, 2009) [J].

Gray, Harry B. .

NATURE CHEMISTRY, 2009, 1 (01) :7-7

[4] Examination of the bonding in binary transiton-metal monophosphides MP (M = Cr, Mn, Fe, Co) by x-ray photoelectron spectroscopy [J].

Grosvenor, AP ;

Wik, SD ;

Cavell, RG ;

Mar, A .

INORGANIC CHEMISTRY, 2005, 44 (24) :8988-8998

[5] DNA-Functionalized Graphene to Guide Growth of Highly Active Pd Nanocrystals as Efficient Electrocatalyst for Direct Formic Acid Fuel Cells [J].

Guo, Chun Xian ;

Zhang, Lian Ying ;

Miao, Jianwei ;

Zhang, Jintao ;

Li, Chang Ming .

ADVANCED ENERGY MATERIALS, 2013, 3 (02) :167-171

[6] [FeFe]-Hydrogenase-Catalyzed H2 production in a photoelectrochemical biofuel cell [J].

Hambourger, Michael ;

Gervaldo, Miguel ;

Svedruzic, Drazenka ;

King, Paul W. ;

Gust, Devens ;

Ghirardi, Maria ;

Moore, Ana L. ;

Moore, Thomas A. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (06) :2015-2022

[7]

Jiang P., 2014, ANGEW CHEM INT EDIT, V53

[8] CoSe2 Nanoparticles Grown on Carbon Fiber Paper: An Efficient and Stable Electrocatalyst for Hydrogen Evolution Reaction [J].

Kong, Desheng ;

Wang, Haotian ;

Lu, Zhiyi ;

Cui, Yi .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (13) :4897-4900

[9] Synthesis of MoS2 and MoSe2 Films with Vertically Aligned Layers [J].

Kong, Desheng ;

Wang, Haotian ;

Cha, Judy J. ;

Pasta, Mauro ;

Koski, Kristie J. ;

Yao, Jie ;

Cui, Yi .

NANO LETTERS, 2013, 13 (03) :1341-1347

[10] An overview of cathode material and catalysts suitable for generating hydrogen in microbial electrolysis cell [J].

Kundu, Anirban ;

Sahu, Jaya Narayan ;

Redzwan, Ghufran ;

Hashim, M. A. .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (04) :1745-1757

← 1 2 3 →