Biomimetic synthesis of the microbial elicitor syringolide 2

被引：32

作者：

Henschke, JP ^{[1
]}

Rickards, RW ^{[1
]}

机构：

[1] AUSTRALIAN NATL UNIV,RES SCH CHEM,CANBERRA,ACT 0200,AUSTRALIA

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 20期

关键词：

D O I：

10.1016/0040-4039(96)00611-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Syringolide 2 (1; n=2), an elicitor metabolite of the bacterial plant pathogen Pseudomonas syringae pv. tomato, has been synthesised in four steps from D-xylulose. The key stage involves triple cyclisation of the putative biosynthetic intermediate 1-(3'-oxodecanoyl)-D-xylulose (9), and provides evidence for the biosynthesis of the syringolides. Copyright (C) 1996 Published by Elsevier Science Ltd

引用

页码：3557 / 3560

页数：4

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