Engineering nanospaces: ordered mesoporous silicas as model substrates for building complex hybrid materials

被引：101

作者：

Ford, DM

Simanek, EE

Shantz, DF

机构：

[1] Texas A&M Univ, Dept Chem Engn, College Stn, TX 77843 USA

[2] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

来源：

NANOTECHNOLOGY | 2005年 / 16卷 / 07期

关键词：

D O I：

10.1088/0957-4484/16/7/022

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

This contribution summarizes investigations of organic-inorganic hybrid materials wherein the inorganic phase is ordered mesoporous silica such as MCM-41 and SBA-15. The review, which covers work performed in the last three years, emphasizes studies of: (1) covalently attached functional groups. (2) new approaches to functionalization, (3) approaches for achieving high densities of uniform functional groups, (4) periodic mesoporous organosilicas (PMOs) with hierarchical ordering, (5) new functional chemistries, and (6) the application of new materials to enantioselective catalysis and emerging areas. The review concludes with the authors outlining some outstanding problems in the field.

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收藏

页码：S458 / S475

页数：18

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