Synthesis of a mannotetraose -: The repeating unit of the cell-wall mannans of Microsporum gypseum and related species of Trychophyton

被引：26

作者：

Heng, LS ^{[1
]}

Ning, J ^{[1
]}

Kong, FZ ^{[1
]}

机构：

[1] Acad Sinica, Ecoenvironm Sci Res Ctr, Beijing 100085, Peoples R China

来源：

JOURNAL OF CARBOHYDRATE CHEMISTRY | 2001年 / 20卷 / 3-4期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1081/CAR-100104864

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A tetrasaccharide, alpha -D-mannopyranosyl-(1 -->2)-alpha -D-mannopyranosyl-(1 -->6)-alpha -D-mannopyranosyl-(1 -->6)-D-maanopyranose (1), the repeating unit of the cell-wall mannans of Microsporum gypseum and related species of Trychophyton, was synthesized using 6-O-acetyl-2,3,4-tri-O-benzoyl-alpha -D-mannopyranosyl trichloroacetimidate (5) and 2-O-acetyl-3,4,6-tri-O-benzoyl-alpha -D-mannopyranosyl trichloroacetimidate (13) as the glycosyl donors in "the inverse Schmidt 'procedure.

引用

页码：285 / 296

页数：12

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