Preparation and characterization of polypyrrole, N-substituted with liquid crystalline moieties

被引：35

作者：

Ibison, P

Foot, PJS

Brown, JW

机构：

[1] School of Applied Chemistry, Kingston University, Kingston-upon-Thames, Surrey KT1 2EE, Penrhyn Road

来源：

SYNTHETIC METALS | 1996年 / 76卷 / 1-3期

基金：

英国工程与自然科学研究理事会;

关键词：

polypyrrole; liquid crystalline moieties; polymerization;

D O I：

10.1016/0379-6779(95)03475-Y

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We describe the synthesis and polymerization of an N-substituted pyrrole. The substituent is an organic spacer chain culminating in a mesogenic cyanobiphenyl group. The monomer molecule is symmetrical, and its polymerization produces effectively exclusive head-to-tail coupling, resulting in increased chemical perfection of the polymer backbone. It is therefore not sensitive to head-tail or head-head coupling effects. The liquid crystallinities of the monomer and polymer have both been examined.

引用

页码：297 / 300

页数：4

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