Synthesis and structure of the first mixed halide-dithiocarbamate complex of Se(II), bromodiethyldithio-carbamatoselenium(II), [Se{(C2H5)(2)NCS2}Br]

被引：2

作者：

Rajashree, S ^{[1
]}

Kumar, RK ^{[1
]}

Udupa, MR ^{[1
]}

Aravamudan, G ^{[1
]}

Seshasayee, M ^{[1
]}

机构：

[1] INDIAN INST TECHNOL,DEPT PHYS,MADRAS 600036,TAMIL NADU,INDIA

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1996年 / 108卷 / 1-4期

关键词：

Se(IV)-thiuram disulfide reaction; bromoselenium(II); dithiocarbamatoselenium(II); bromodiethyldithiocarbamatoselenium(II);

D O I：

10.1080/10426509608029641

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound, SeLBr [L(-) = diethyldithiocarbamate, (C2H5)(2)NCS2-] is the first example of Se(II) complex featuring a dithiocarbamate and a halide. It was obtained by the reaction of Se(IV)bromide with tetraethylthiuram disulfide in a methanol solution containing hydrobromic acid. The structure determination of the compound shows it to be polymeric with bromine being the bridging ligand. The crystals of SeLBr are monoclinic with a = 10.391(3), b = 8.434(4), c = 12.030(2) Angstrom, beta = 108.10(2)degrees, V = 1002.15 Angstrom(3), Z = 4 and space group, P2(1)/n; R = 0.073, R(W) = 0.074.

引用

页码：85 / 92

页数：8

共 39 条

[1] CRYSTAL AND MOLECULAR STRUCTURE OF SELENIUM DI(MORPHOLYLDITHIOCARBAMATE) [J].

ANDERSON, OP ;

HUSEBYE, S .

ACTA CHEMICA SCANDINAVICA, 1970, 24 (09) :3141-&

[2] NICKEL(II) AND COPPER(II) COMPLEXES OF MONO-ETHANOL-DITHIOCARBAMIC AND DI-ETHANOL-DITHIOCARBAMIC ACID [J].

ANNUAR, B ;

HILL, JO ;

MAGEE, RJ .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1974, 36 (06) :1253-1257

[3] COMPLEXES OF TE(IV), TE(II) AND SE(II) WITH METHYL BETA-HYDROXYETHYLDITHIOCARBAMATE [J].

ARAVAMUDAN, G ;

JANAKIRAM, C ;

SEJEKAN, BG .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1978, 5 (02) :185-188

[4] REACTION OF BIS(MORPHOLINOSELENOCARBONYL) TRISELENIDE WITH IODINE - EXISTENCE OF A 1-1 CHARGE-TRANSFER PRECURSORY ADDUCT IN SOLUTION IN AN OXIDATIVE REACTION - ISOLATION AND CRYSTAL-STRUCTURE OF THE NEW (N-MORPHOLINECARBODISELENOATO)SELENIUM(II) IODIDE [J].

BIGOLI, F ;

LEPORATI, E ;

PELLINGHELLI, MA ;

CRISPONI, G ;

DEPLANO, P ;

TROGU, EF .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (08) :1763-1769

[5] PREPARATION AND CRYSTAL-STRUCTURES OF CIS-DICHLOROBIS-(THIOUREA)SELENIUM(II) AND CIS-DIBROMOBIS(THIOUREA)SELENIUM(II) [J].

BJORNEVAG, SV ;

HAUGE, S .

ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1983, 37 (03) :235-240

[6] STRUCTURAL STUDIES OF METAL DITHIOCARBAMATES .3. CRYSTAL AND MOLECULAR STRUCTURE OF ZINC DIETHYLDITHIOCARBAMATE [J].

BONAMICO, M ;

MAZZONE, G ;

VACIAGO, A ;

ZAMBONEL.L .

ACTA CRYSTALLOGRAPHICA, 1965, 19 :898-&

[7] CRYSTAL-STRUCTURES OF METHYLXANTHATES OF DIVALENT SULFUR, SELENIUM, AND TELLURIUM [J].

BRONDMO, NJ ;

ESPERAS, S ;

GRAVER, H ;

HUSEBYE, S .

ACTA CHEMICA SCANDINAVICA, 1973, 27 (02) :713-715

[8]

BUSEV AI, 1964, TALANTA, V11, P485

[9] PREPARATION OF IODOTRIS(DITHIOCARBAMATO)TELLURIUM(IV) COMPLEXES, AND CRYSTAL-STRUCTURE OF IODOTRIS(PIPERIDINE-1-CARBODITHIOATO)TELLURIUM(IV) [J].

CHIDAMBARAM, S ;

ARAVAMUDAN, G ;

SESHASAYEE, M ;

SNOW, MR ;

TIEKINK, ERT .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1989, 42 (06) :969-975

[10]

CLARK ER, 1974, J INORG NUCL CHEM, V36, P3680

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