Synthesis and characterization of luminescent osmium(II) carbonyl complexes based on chelating dibenzoylmethanate and halide ligands

被引：24

作者：

Chen, YL

Sinha, C

Chen, IC

Liu, KL

Chi, Y ^{[1
]}

Yu, JK

Chou, PT

Lu, TH

机构：

[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 300, Taiwan

[2] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan

[3] Natl Tsing Hua Univ, Dept Phys, Hsinchu 300, Taiwan

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 24期

关键词：

D O I：

10.1039/b308340c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Octahedral Os(II) complexes 1-5 with formula [Os(CO)(3)X(dbm)] are prepared through utilization of both solid-state pyrolysis and ligand exchange reactions. These complexes exhibit prominent (3)pi-pi* phosphorescence with unusually long lifetimes (29-64 mus) and high quantum yields (0.08-0.13).

引用

页码：3046 / 3047

页数：2

共 22 条

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