Unprecedented replacement of bridging oxygen atoms in polyoxometalates with organic imido ligands

被引：98

作者：

Hao, Jian ^{[1
,2
]}

Xia, Yun ^{[3
,4
]}

Wang, Longsheng ^{[2
]}

Ruhlmann, Laurent ^{[1
]}

Zhu, Yulin ^{[2
]}

Li, Qiang ^{[2
]}

Yin, Panchao ^{[2
]}

Wei, Yongge ^{[2
]}

Guo, Hongyou ^{[3
]}

机构：

[1] Univ Paris 11, Chim Phys Lab, F-91405 Orsay, France

[2] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China

[3] Beijing Univ Chem Technol, Dept Chem, Beijing 102413, Peoples R China

[4] China Inst Atom Energy, Dept Sci & Technol Informat, Beijing 102413, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 14期

关键词：

bridging groups; imido ligands; organic-inorganic hybrid composites; polyoxometalates;

D O I：

10.1002/anie.200704546

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Building bridges: Two arylimido derivatives of hexamolybdate, containing unprecedented bridging imido ligands, have been synthesized and structurally characterized. Their 1H NMR and UV/Vis spectra distinguish them from related terminally coordinated derivatives. Such compounds extend the range of organoimido polyoxometalate coordination chemistry, providing insight into the mechanism of oxo metathesis in the Lindqvist polymolybdate. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2626 / 2630

页数：5

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