Hydrogenlike Rydberg electrons orbiting molecular clusters

被引：19

作者：

Neuhauser, R

Siglow, K

Neusser, HJ

机构：

[1] Tech Univ Munich, Inst Phys & Theoret Chem, D-85748 Garching, Germany

[2] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

PHYSICAL REVIEW LETTERS | 1998年 / 80卷 / 23期

关键词：

D O I：

10.1103/PhysRevLett.80.5089

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Series of Rydberg states up to n > 100 are observed for the first time in weakly bound, polyatomic van der Waals clusters. Cross-correlation calculations of the dense spectra with simulated Rydberg series reveal a long-lived (mu s), hydrogenlike series of Rydberg states. The slightly different series limits are interpreted as single quantum states in the dense rovibrational level manifold of the weakly bound cluster cation.

引用

页码：5089 / 5092

页数：4

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